Synthesis and electrochemistry of phthalocyanines bearing [(3,4-dimethoxybenzyl)oxy] groups

Authors : İpek ÖMEROĞLU, Zekeriya BIYIKLIOĞLU

Pages : 347-0

Doi:10.3906/kim-1408-71

View : 24 | Download : 9

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :In this study peripherally tetra-substituted metal-free, metallophthalocyanines bearing insert ignore into journalissuearticles values(3,4-dimethoxybenzyl); oxy groups have been synthesized and characterized. Electrochemical properties of novel phthalocyanines 4, 5, 6, and 7 were determined by cyclic and square wave voltammetry in order to define their possible applications in different electrochemical technologies. Co^{II} and Ti^{IV}O metal ions behave as redox active cations in the core of the CoPc and TiOPc complexes, respectively. Voltammetric studies revealed that phthalocyanines have reversible/irreversible redox processes, which are the main requirement for the technological usage of these compounds.
Keywords : Phthalocyanine, oxotitanium, cobalt, electrochemistry, voltammetry