Activity of $\gamma $-Al$_{2}$O$_{3}$-based Mn, Cu, and Co oxide nanocatalysts for selective catalytic reduction of nitric oxide with ammonia

Authors : Parvaneh Nakhostin PANAHI, Gerard DELAHAY

Pages : 272-281

View : 15 | Download : 6

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :Our studies on the selective catalytic reduction of NO insert ignore into journalissuearticles values(SCR-deNO); properties of M/$\gamma $-Al$_{2}$O$_{3}$ insert ignore into journalissuearticles values(M = Mn, Co, Cu); nanocatalysts are presented. All catalysts were prepared by homogeneous deposition precipitation using urea as the precursor for the precipitating agent. The SCR activity followed the order Mn/$\gamma $-Al$_{2}$O$_{3} >$ Cu/$\gamma $-Al$_{2}$O$_{3} >$ Co/$\gamma $-Al$_{2}$O$_{3}$. The nanocatalysts were characterized with respect to their texture insert ignore into journalissuearticles values(N$_{2}$-BET);, particle size insert ignore into journalissuearticles values(TEM);, reducibility insert ignore into journalissuearticles values(H$_{2}$-TPR);, and acidity insert ignore into journalissuearticles values(NH$_{3}$-TPD);. The TEM analysis revealed that the metal species have superior dispersion with less agglomeration and sintering on $\gamma $-Al$_{2}$O$_{3}$ support. The H$_{2}$-TPR results confirmed that the Mn/$\gamma $-Al$_{2}$O$_{3}$ nanocatalyst contains various oxidation states of manganese, which is useful for the catalyst to maintain the DeNO activities. The NH$_{3}$-TPD studies indicated that the addition of transition metal can significantly increase the surface acidity and Mn/$\gamma $-Al$_{2}$O$_{3}$ showed the most adsorbed sites of NH$_{3}$. Characterization results indicated that the acidity and the redox properties of the catalyst play important roles in the final catalytic activity in the SCR-NO process.
Keywords : NO, NH 3 SCR, transition metals, gamma Al 2 O 3, nanocatalyst