Synthesis of nonperipherally tetra-[5-(diethylamino)-2-formylphenoxy] substituted metallophthalocyanines and their electrochemistry

Authors : Turgut KELES, Dilek UNLUER, Zekeriya BİYİKLİOGLU, Yasemin UNVER

Pages : 17-25

View : 18 | Download : 11

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :3-[5-insert ignore into journalissuearticles values(diethylamino);-2-formylphenoxy]phthalonitrile insert ignore into journalissuearticles values(n-TY-CN);, metallophthalocyanines n-TY-Co, n-TY-Cu, and n-TY-Mn bearing [5-insert ignore into journalissuearticles values(diethylamino);-2-formylphenoxy] groups at nonperipheral positions were prepared for the first time. These compounds were characterized with IR, NMR insert ignore into journalissuearticles values(only for n-TY-CN);, mass and UV-vis insert ignore into journalissuearticles values(except n-TY-CN); spectroscopy. Voltammetric characterizations of n-TY-Co, n-TY-Cu, and n-TY-Mn revealed that while n-TY-Co, n-TY-Cu, and n-TY-Mn showed characteristic Pc ring and/or metal-based reduction reaction, n-TY-Co, n-TY-Cu, and n-TY-Mn were coated on the working electrode during the oxidation processes owing to the cationic electropolymerizations of the [5-insert ignore into journalissuearticles values(diethylamino);-2-formylphenoxy] substituents.
Keywords : Synthesis, diethylamino, phthalocyanine, electrochemistry