Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway

Authors : Priyamvada SHARMA, Riya SAİLANİ, Anita MEENA, Chandra Lata KHANDELWAL

Pages : 950-970

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Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :The kinetic pathway of oxidation of crotyl alcohol by sodium salt of N-chloro-4-methylbenzene sulphonamide insert ignore into journalissuearticles values(chloramine-T); in acidic and alkaline medium has been studied. The speciation of chloramine-T has been made to suggest a proper and reasonable reaction mechanism. The thermodynamic quantities such as activation energy and activation entropy are evaluated in acidic as well as in catalysed alkaline medium. An anticipated reaction mechanism has been suggested.
Keywords : transfer reaction, reaction kinetics, mechanism, osmium VIII, catalysis, crotyl alcohol, chloramine T