Magic Gold Nanotubes

Authors : R Tuğrul SENGER, Sefa DAĞ, Salim ÇIRACI

Pages : 269-276

Doi:10.3906/sag-1111-45

View : 19 | Download : 9

Publication Date : 0000-00-00

Article Type : Research Paper

Abstract :In recent ultra-high-vacuum transmission-electron-microscopy experiments evidence is found for the formation of suspended gold single-wall nanotubes insert ignore into journalissuearticles values(SWNTs); composed of five helical strands. Similar to carbon nanotubes, the insert ignore into journalissuearticles values(n,m); notation defines the structure of the gold SWNTs. Experimentally, only the insert ignore into journalissuearticles values(5,3); tube has been observed to form among several other possible alternatives. Using first-principles calculations we demonstrate that gold atoms can form both freestanding and tip-suspended, chiral, single-wall nanotubes. Although freestanding, infinite insert ignore into journalissuearticles values(5,5); tube is found to be energetically the most favorable, the experimentally observed insert ignore into journalissuearticles values(5,3); tube, suspended between two tips, corresponds to a local minimum in the variation of string-tension with the radius of the structure, which explains the experimental finding. Similarly, we predict the insert ignore into journalissuearticles values(4,3); tube as a favorable structure yet to be observed experimentally. Analysis of band structure, charge density, and quantum ballistic conductance suggests that the current on these nanowires is less chiral than expected, and there is no direct correlation between the numbers of conduction channels and helical strands.
Keywords : Gold Nanotube, Quantum Conductance