Dispersive liquid-liquid microextraction for the spectrophotometric determination of Fe3+ with a water soluble Cu(II) phthalocyanine compound

Authors : Yasemin ÇAĞLAR

Pages : 70-76

Doi:10.51435/turkjac.1314130

View : 68 | Download : 33

Publication Date : 2023-06-30

Article Type : Research Paper

Abstract :DLLME, which is a method that minimizes organic solvent consumption and waste generation, is frequently used for trace analyte determination. In the present work, a simple, selective and sentsitive spectrophotometric method based on the dispersive liquid-liquid microextraction was reported. The procedure is based on the formation of a 1:1 complex between Fe3+ and a water-soluble Cuinsert ignore into journalissuearticles values(II); phthalocyanine and then extraction of this complex into dichloromethane by dispersive effect of acetone. The experimental parameters that effecting the DLLME such as amount of extractive and disperser solvents, pH, salt concentration, Cuinsert ignore into journalissuearticles values(II); phthalocyanine concentration and centrifuging time and rate were optimized. The linear range of the method is 0.4-70.0 ngmL-1 with a good correlation coefficient insert ignore into journalissuearticles values(R2); of 0.9912. The limits of detection insert ignore into journalissuearticles values(LOD); and quantification insert ignore into journalissuearticles values(LOQ); is 0.47 and 1.86 ngmL-1. The relative standart deviation insert ignore into journalissuearticles values(RSD, %); of the method for 40 ngmL-1 Fe3+ in sample solution insert ignore into journalissuearticles values(n=11); was 1.4% and the enrichment factor was calculated 240.
Keywords : DLLME, spectrophotometry, iron, Cu II, phthalocyanine

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