Rare Earth Element Potentials of Red-Colored Eocene Kazmaca and Late Eocene–Early Miocene İncik and Bayındır Formations (Kırıkkale, Türkiye)

Authors : Berna Yavuz Pehlivanlı, Menevşe Altan
Pages : 130-148
Doi:10.19111/bulletinofmre.1811818
View : 106 | Download : 164
Publication Date : 2025-12-23
Article Type : Research Paper
Abstract :Thered-colored sedimentary rocks of the Kazmaca, İncik, and Bayındır formations, particularly the red mudstones, exhibit noteworthy enrichment in Rare Earth Elements (REEs) and uranium. These finegrained units were deposited in low-energy lacustrine to shallow-marine environments, where redoxsensitive geochemical processes played a central role in elemental mobilization and accumulation. Mineralogical and geochemical analyses, including XRD, XRF, and ICP-MS, identified the uraniumbearing mineral Fourmarierite, confirming the presence of uranium mineralization. This finding is supported by elevated Cu/Al ratios, increased Fe concentrations, and trace-element distributions indicative of a redox-controlled diagenetic environment. The high Fe concentrations and Cu/Al ratiosact as geochemical proxies for REE-hosting phases. The depositional setting, characterized by low dissolved oxygen levels, likely reflects a warm and humid paleoclimate that enhanced chemical weathering and facilitated the mobilization and subsequent precipitation of uranium and REEs. Notably, dark-colored mudstone interbeds within the sandstone sequences exhibit localized uranium accumulation, which may represent precursor zones for secondary REE mineralization. These findings underscore the importance of redox conditions and climatic factors in controlling REE and uranium enrichment in red bed sequences. The presence of Fourmarierite, in conjunction with distinctive geochemical signatures, suggests a significant potential for REE exploration in these formations.
Keywords : Rare Earth Elements (REEs), Fourmarierite, Red Sedimentary Rocks, Kazmaca Formation, İncik Formation, Bayındır Formation.

ORIGINAL ARTICLE URL